Synthesis of ?-substituted carbonyl compounds from DMSO-mediated oxidation of enynamides: mechanistic insights and carbon- and hetero-functionalizations

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Chem. Sci., 2019, Advance ArticleDOI: 10.1039/C9SC03663F, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Quynh H. Nguyen, Nguyen H. Nguyen, Hanbyul Kim, Seunghoon Shin1,3-Enynamides underwent oxygenative coupling with carbon- and heteroatom nucleophiles with high remote selectivity. Kinetic analysis revealed a continuum mechanism between concerted SN2?? and via a carbocation, depending on the nucleophiles used.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry

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