Mechanistic understanding of [Rh(NHC)]-catalyzed intramolecular [5+2] cycloadditions of vinyloxiranes and vinylcyclopropanes with alkynes

Org. Biomol. Chem., 2018, Accepted ManuscriptDOI: 10.1039/C8OB01117F, PaperHuan Zhou, Botao Wu, Jun-An Ma, Yanfeng DangZhang and co-workers have recently advanced the carbon [5+2] cycloaddition of vinylcyclopropane and alkyne (VCP-alkyne) to the hetero-[5+2] cycloaddition of vinyloxirane with alkyne (VOR-alkyne). Herein, we present a systematic computational...The content of this RSS Feed (c) The Royal Society of Chemistry

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