A flexible, redox-active macrocycle enables the electrocatalytic reduction of nitrate to ammonia by a cobalt complex

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Chem. Sci., 2018, 9,4950-4958DOI: 10.1039/C8SC00721G, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Song Xu, Daniel C. Ashley, Hyuk-Yong Kwon, Gabrielle R. Ware, Chun-Hsing Chen, Yaroslav Losovyj, Xinfeng Gao, Elena Jakubikova, Jeremy[space]M. SmithMechanistic investigations into electrocatalytic nitrate reduction by a cobalt complex reveal the critical role played by the flexible, redox-active ligand.The content of this RSS Feed (c) The Royal Society of Chemistry

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