• user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'ad:0:aurora:http://a.slickfinder.com/' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1560923807, expire = -1, headers = '', serialized = 0 WHERE cid = 'ad:0:aurora:http://a.slickfinder.com/' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'counter:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = 'a:2:{s:7:\"subject\";s:7:\"Counter\";s:7:\"content\";s:335:\"<ul id=\"counter\"><li>Site Counter: 9,499,336</li><li>Unique Visitor: 429,177</li><li>Registered Users: 1</li><li>Unregistered Users: 0</li><li>Blocked Users: 0</li><li>Published Nodes: 314,283</li><li>Unpublished Nodes: 6,329</li><li>Server IP: 216.53.213.119</li><li>Your IP: 54.85.162.213</li><li>Since: 2014-07-03 13:09:52</li></ul>\";}', created = 1560923815, expire = -1, headers = '', serialized = 1 WHERE cid = 'counter:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
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  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1560923815, expire = -1, headers = '', serialized = 0 WHERE cid = 'tribune:1:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'user:2:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = 'a:2:{s:7:\"subject\";s:9:\"Who\'s new\";s:7:\"content\";s:126:\"<div class=\"item-list\"><ul><li class=\"first last\"><a href=\"/users/admin\" title=\"View user profile.\">admin</a></li>\n</ul></div>\";}', created = 1560923815, expire = -1, headers = '', serialized = 1 WHERE cid = 'user:2:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'book:0:aurora:r.1:http://a.slickfinder.com/' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
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  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'pagination:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
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  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'recipe:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
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Toxicological effects of ingested nanocellulose in in vitro intestinal epithelium and in vivo rat models

Environ. Sci.: Nano, 2019, Accepted ManuscriptDOI: 10.1039/C9EN00184K, PaperGlen DeLoid, Xiaoqiong Cao, Ramon M Molina, Daniel Imbassahy Silva, Kunal Bhattacharya, Kee Woei Ng, Joachim Loo, Joseph Brain, Philip DemokritouCellulose is widely used as a thickener and filler in foods and drugs. It has been designated “generally regarded as safe” (GRAS). Nanocellulose (NC) has many additional potential applications designed...The content of this RSS Feed (c) The Royal Society of Chemistry

Neuronal damage induced by nanopolystyrene particles in nematode Caenorhabditis elegans

Environ. Sci.: Nano, 2019, Accepted ManuscriptDOI: 10.1039/C9EN00473D, PaperMan Qu, Yan Kong, Yujie Yuan, Dayong WangThe potential adverse effects of nanoplastics have gradually received the great attention. We here employed Caenorhabditis elegans to investigate the possible neurotoxicity of nanopolystyrene particles on development and function of...The content of this RSS Feed (c) The Royal Society of Chemistry

Inhibitions of HMGB1 and TLR4 alleviate DINP-induced asthma in mice

Toxicol. Res., 2019, Accepted ManuscriptDOI: 10.1039/C9TX00048H, PaperYun-Ho Hwang, Yongjin Lee, Man-Jeong Paik, Sung-Tae YeeWe studied the effects of high mobility group box chromosomal protein 1 (HMGB1) and toll-like receptor (TLR4) in diisonoyl phthalate (DINP)-induced asthma. Mice with DINP-induced asthma were treated with a...The content of this RSS Feed (c) The Royal Society of Chemistry

Preparation of a Large-sized Highly Flexible Carbon Nanohoop

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00763F, PaperYuta Nakagawa, Ryuta Sekiguchi, Jun Kawakami, Shunji ItoPreparation of large-sized carbon nanohoops 1 and 2 was established by Pt-mediated macrocyclization of diborylated hexa-peri-hexabenzocoronene (HBC) derivative contained four mesityl substituents at the periphery.

NIS-mediated oxidative arene C(sp2)–H amidation toward 3,4-dihydro-2(1H)-quinolinone, phenanthridone, and N-fused spirolactam derivatives

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB01277J, CommunicationLingang Wu, Yanan Hao, Yu-Xiu Liu, Qingmin WangA new radical-mediated intramolecular arene C(sp2)–H amidation of 3-phenylpropanamides or [1,1'-biphenyl]-2-carboxamides was developed to prepare a series of 3,4-dihydro-2(1H)-quinolinone and phenanthridone derivatives in moderate to excellent yields (33–92%).

Palladium(II)-Catalyzed Regioselective Ortho-C_H Bromination/Iodination of Arylacetamides via in situ Generated Imidic Acid as Directing Group: Mechanistic Exploration

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB01082C, PaperYogesh Jaiswal, Yogesh Kumar, Amit KumarIn the present study, we report palladium(II)-catalyzed regioselective ortho-C-H bromination/iodination of challenging arylacetamide derivatives using N-halo-succinimide as halogenating agents.

Amine-Tethered Phenylboronic Acid-Enabling Ring-Opening Strategy for Carbon Chain Elongation from Double Aldol Cyclic Hemiacetals

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB01263J, CommunicationYamato Kanzaki, Yuki Hirao, Harunobu Mitsunuma, Motomu KanaiThe addition of carbon nucleophiles to cyclic hemiacetal forms of double aldols is a promising approach toward the synthesis of structurally attractive 1,3-polyol derivatives. Cyclic hemiacetals are generally unreactive to...The content of this RSS Feed (c) The Royal Society of Chemistry

Organocatalytic Asymmetric Synthesis of Dihydrofuran-Spirooxindoles from Benzylidene Malononitriles and Dioxindoles

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB01199D, CommunicationSubhas Chandra Pan, Megha Balha, Buddhadeb MondalThe first organocatalytic enantioselective synthesis of dihydrofuran-spirooxindoles having linkage at 2-position of dihydrofuran motif has been developed. Dioxindoles and benzylidene malononitriles were employed in this method.

Diastereoselective synthesis of ?-dicarbonyl cyclopropanes via a lanthanide amide-catalysed reaction

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00732F, PaperWenxi Sun, Cheng Peng, Zhigang Yao, Fan XuLanthanide bis(trimethylsilyl)amides, [(Me3Si)2N]3Ln(?-Cl)Li(THF)3, were used as efficient catalysts for a one-pot reaction of ?-ketoesters, dialkyl phosphite, and activated alkenes to produce ?-dicarbonyl cyclopropanes in moderate to high yields. The reaction...The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, Self-assembly and pH-responsive Fluorescent Enhancement of Alternating Amphiphilic Copolymer with Azobenzene Pendants

Polym. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9PY00634F, PaperJiacheng Wu, Binbin Xu, Zhenghui Liu, Yuan Yao, Qixin Zhuang, Shaoliang LinIn this work, a novel alternating amphiphilic copolymer (AAC) P(EG4-a-NAzoOMe) with azobenzene pendants was synthesized through the azide-alkyne click reaction. This proposed AAC possesses unusual photo- and pH- responsive behaviors...The content of this RSS Feed (c) The Royal Society of Chemistry

Poly(N-isopropylacrylamide) Derived Nanogels Demonstrated Thermosensitive Self-assembly and GSH-triggered Drug Release for Efficient Tumor Therapy

Polym. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9PY00537D, PaperJiaojiao Chen, Ming Wu, Hanitrarimalala Veroniaina, Subhankar Mukhopadhyay, Juequan Li, Ziheng Wu, Zhenghong Wu, Xiaole QiRecently, interest in stimuli-responsive core-shell nanogels as drug delivery systems for tumor therapy has increased.

Encapsulation of lipophilic fragrance by polymerization of the intermediate aqueous phase of an oil-in-water-in-oil (O/W/O) double emulsion

Polym. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9PY00528E, PaperValerie Heroguez, Margot Stasse, Tiphaine Ribaut, Veronique SchmittThis paper deals with the encapsulation of lipophilic compounds in a double oil-in-water-in-oil (O/W/O) emulsion. Such encapsulation is of special interest in cosmetics where fragrance is generally a mixture of...The content of this RSS Feed (c) The Royal Society of Chemistry

MH17 plane crash: Investigators 'expected to name four suspects'

Ukraine says the suspects will be named by the Dutch-led investigation into the 2014 plane downing.

Donald Trump formally launches 2020 re-election bid

The president told thousands of supporters in Florida they were going to "keep America great".

US-China trade war: Officials to resume talks before G20

Mr Trump says he will have an "extended meeting" with Chinese President Xi Jinping at the G20 next week.

8K and the quest to express the 'real'

To see is to believe: 8K resolution will express new details comparable to 'hyperrealism' oil paintings, according to Professor Yungkyung Park of Ewha Woman's University, and its commercialisation will be an important milestone in the evolution of TV visual experience.

UK PM hopefuls in TV clash over Brexit deadline

Boris Johnson says it is "eminently feasible" to leave the EU by 31 October, but his rivals say more time may be needed.

California wildfires: Power company agrees to pay $1bn for damage

Pacific Gas & Electric Corp are facing billions of dollars worth of lawsuits over the fires.

Facebook asked by lawmakers to pause Libra cryptocurrency project

Congresswoman Maxine Waters asked Facebook to halt movement of its Libra project until hearings can be held to examine concerns, while French Finance Minister has called for tighter cryptocurrency regulation.

Singapore sees drop in common security threats, but foresees more data breaches

Cyber Security Agency says the number of common cyber threats, including website defacements and phishing, dipped in Singapore last year, but expects to see more frequent data breaches and disruptive attacks against the cloud in the near future.

How America overthrew Guatemala's reformist president

Accused of being a communist, Guatemala's president was toppled in a US-led coup

Viewpoint: How the British reshaped India's caste system

A complex system of beliefs and social identities was oversimplified by colonisers, writes Sanjoy Chakravorty.

Why are Nike trainers washing up on beaches?

From Bermuda and the Azores to Ireland and France, large numbers of shoes are washing ashore.

Oxford University accepts £150m from US private equity boss

Stephen Schwarzman, a confidant of President Trump, makes the largest ever donation to a UK university.

Sudan: Young musicians' hopes and fears for the future

Young musicians in Khartoum talk to the BBC about their hopes following the military crackdown.

Women's World Cup 2019: All the goals as Marta makes history, Kerr hits four & Jamaica celebrate

Watch all the best bits from day 12 of the Women's World Cup featuring Marta's history-making goal and incredible scenes after Jamaica score their first ever World Cup goal.

Should we dislike the 'Like' button?

Social media companies know approval can be addictive, so how should we manage the compulsion to be liked?

Piracy in West Africa: The world's most dangerous seas?

The West African coast has long been a target for pirates, but it's getting even more dangerous.

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