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Humic acid mitigated toxicity of graphene-family materials to algae through reducing oxidative stress and heteroaggregation

Environ. Sci.: Nano, 2019, Accepted ManuscriptDOI: 10.1039/C9EN00067D, PaperJian Zhao, Yue Li, Xuesong Cao, Chuntong Guo, Lina Xu, Zhenyu Wang, Juan Feng, Huimin Yi, Baoshan XingGraphene-family materials (GFMs) will be released into natural aquatic environments during their increasing applications, thus likely inducing adverse effects on aquatic organisms. This work systematically investigated the effect of natural...The content of this RSS Feed (c) The Royal Society of Chemistry

Experimental and geochemical simulation of nickel carbonate mineral precipitation by carbonate-laden ureolytic fungal culture supernatants

Environ. Sci.: Nano, 2019, Accepted ManuscriptDOI: 10.1039/C9EN00385A, PaperQianwei Li, Daoqing Liu, Chunmao Chen, Zhiguo Shao, Huazhen Wang, Jicheng Liu, Qiangbin Zhang, Geoffrey Michael GaddUreolytic microorganisms have attracted much interest for the bioprecipitation, removal and biorecovery of toxic metals from aqueous solution but little is known about the distribution of cationic/anionic components or quantification...The content of this RSS Feed (c) The Royal Society of Chemistry

Synergistic catalysis of N vacancies and ~5 nm Au nanoparticles promoted highly electrochemical determination of lead(II) at Au/N-Deficient-C3N4 nanocomposite

Environ. Sci.: Nano, 2019, Accepted ManuscriptDOI: 10.1039/C9EN00114J, PaperXing-Jiu Huang, Wen-Yi Zhou, Xiang-yu Xiao, Shi-Hua Chen, Shan-Shan Li, Jian WangMost of nanomaterials with good adsorption properties are restricted from electrochemical detection applications due to the lack of active sites and poor electrocatalysis reactivity. Here, we found a synergistic catalysis...The content of this RSS Feed (c) The Royal Society of Chemistry

A non-damaging purification method: decoupling the toxicity of multi-walled carbon nanotubes and their associated metal impurities

Environ. Sci.: Nano, 2019, Accepted ManuscriptDOI: 10.1039/C8EN01276H, PaperChristian Darne, Alexandre Desforges, Nawal Berrada, Caroline Fontana, Yves Guichard, Laurent Gaté, Dominique Begin, François Le Normand, Fabrice Valsaque, Jaafar Ghanbaja, Jérôme Gleize, Brigitte VigoloMulti walled carbon nanotubes (MWCNTs) are purified by a gas-phase method allowing selective removal of the metallic impurities (Fe and Al catalyst residues) while the MWCNTs remain untouched.

Synthesis of Cyclic gem-Dinitro Compounds via Radical Nitration of 1,6-Diynes with Fe(NO3)3.9H2O

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00431A, CommunicationWanzhi Chen, Xiaofei Yi, Kai Chen, Wei Chen, Miaochang Liu, Huayue WuCyclic gem-dinitro compounds were obtained via nitration of 1,6-diynes using Fe(NO3)3.9H2O as the nitating agent. The reaction proceeds at room temperature using cheap nitrating agent. A number of gem-dinitro cyclic...The content of this RSS Feed (c) The Royal Society of Chemistry

Diversity of mechanisms in Ras-GAP catalysis of guanosine triphosphate hydrolysis revealed by molecular modeling

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00463G, PaperBella L Grigorenko, Ekaterina Kots, Alexander NemukhinMechanism of the deceptively simple reaction of guanosine triphosphate (GTP) hydrolysis catalyzed by the cellular protein Ras in complex with the activating protein GAP is an important issue because of...The content of this RSS Feed (c) The Royal Society of Chemistry

Non-Directed Copper-Catalyzed Regioselective C-H Sulfonylation of Phenothiazines

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00705A, Paperkedong yuan, Caiyan Liu, Yongli ShenWe develop a simple and general method for sulfonylation of phenothiazines under CuI catalysis. The broad scope from aryl/alkyl sulfonyl chlorides was applicapable to produce C3 sulfonylation products of phenothiazines...The content of this RSS Feed (c) The Royal Society of Chemistry

Regioselective and oxidant-free sulfinylation of indoles and pyrroles with sulfinamides

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00526A, PaperYuan-Zhao Ji, Jin-Yu Zhang, Hui-Jing Li, Chunguang Han, Yi-Kun Yang, Yan-Chao WuAn unexpected time-controlled highly selective C3- or C2-sulfinylation of pyrroles with sulfinamides is reported for the first time. The sulfinylation of indoles with sulfinamides using this protocol is oxidant-free and...The content of this RSS Feed (c) The Royal Society of Chemistry

Fusaresters A–E, new ?-pyrone-containing polyketides from fungus Fusarium sp. Hungcl and structure revision of fusariumin D

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00534J, PaperJiaojiao Gong, Chunmei Chen, Shuyuan Mo, Junjun Liu, Wenjing Wang, Yi Zang, Huaqiang Li, Chenwei Chai, Hucheng Zhu, Zhengxi Hu, Jianping Wang, Yonghui ZhangMarine-derived fungi have been regarded as an under-explored and promising reservoir of structurally novel and bioactive natural products.

Acid Catalysed Rearrangement of Isobenzofurans to Angularly Fused Phthalides

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00708C, CommunicationBeeraiah Baire, Bhavani Shankar Chinta, Soniya GandhiAn acid catalysed, cascade process for the construction of angularly fused polycyclic phthalides from isobenzofurans under transition metal free conditions has been reported. This process is very general for divergent...The content of this RSS Feed (c) The Royal Society of Chemistry

?-Glucuronidase Triggers Extracellular MMAE Release from an Integrin-Targeted Conjugate

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00617F, CommunicationPaula López Rivas, Christoph Müller, Christian Breunig, Torsten Hechler, Andreas Pahl, Daniela Arosio, Laura Belvisi, Luca Pignataro, Alberto Dal Corso, Cesare GennariA non-internalizing ?v?3 integrin ligand was conjugated to the anticancer drug MMAE through a ?-glucuronidase-responsive linker.

Cobalt-catalyzed cyclization with the introduction of cyano, acyl and aminoalkyl groups

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00637K, PaperHiroto Hori, Shigeru Arai, Atsushi NishidaAn efficient synthesis of carbo- and heterocycles using C=C, C=O and C=N bonds under cobalt catalysis is described. The substituents on olefins are key for controlling regio- and chemoselectivity in...The content of this RSS Feed (c) The Royal Society of Chemistry

Tuning photosensitized singlet oxygen production from microgels synthesized by polymerization in aqueous dispersed media

Polym. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9PY00157C, PaperLuca Petrizza, Mickael LeBechec, Emile Decompte, Hind El-Hadri, Sylvie Lacombe, Maud SaveNovel sub-micronic photoactive polymer colloids grafted with Rose Bengal (RB) photosensitizer were designed to promote singlet oxygen production from a supported organic photosensitizer.

Nanopore Separator of Crosslinked Poly (Propylene Glycol)-co-Pentaerythritol Triacrylate for Effectively Suppressing the Polysulfide Shuttle in Li-S battery

Polym. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9PY00206E, PaperHaixia Li, Wentao Tang, Yi Fu Huang, Wen Hong Ruan, Ming Qiu ZhangLithium-sulfur (Li-S) battery has attracted tremendous attention as the next generation of lithium battery. In the battery construction, nanopore separator can improve the performance of the Li-S battery by working...The content of this RSS Feed (c) The Royal Society of Chemistry

Structure and Luminescence Properties of Supramolecular Polymers of Amphiphilic Aromatic Thioether-Peptide Conjugates in Water

Polym. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C8PY01712C, PaperPatrick Ahlers, Christian Götz, Steffen Riebe, Michael Zirbes, Matthias Jochem, Daniel Spitzer, Jens Voskuhl, Thomas Basche, Pol BeseniusWe present the preparation of luminophore-peptide conjugates that self-assemble into supramolecular polymers in neutral buffer.

Synthesis and solution behaviour of dual light- and temperature-responsive poly(triethylene glycol-co-spiropyran) copolymers and block copolymers

Polym. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9PY00458K, PaperOliver Grimm, Sarina Claudia Maßmann, Felix Helmut SchacherWe herein report on the synthesis and characterization of materials featuring a dual-responsive copolymer segment consisting of photo-responsive spiropyran (SPA) and temperature-responsive triethylene glycol acrylate (TEGA). The copolymers contain 0...The content of this RSS Feed (c) The Royal Society of Chemistry

Ixocarpalactone A from dietary tomatillo inhibits pancreatic cancer growth by targeting PHGDH

Food Funct., 2019, Accepted ManuscriptDOI: 10.1039/C9FO00394K, PaperMengzhu Zheng, Jing Guo, Jiamin Xu, Kaiyin Yang, Ruotian Tang, Xiaoxia Gu, Hua Li, Lixia Chen3-Phosphoglycerate dehydrogenase (PHGDH) catalyzes the first rate-limiting step for the synthesis of glucose-derived serine by converting 3-phosphoglycerate (3-PG) to phosphohydroxypyruvate (p-Pyr), which has been reported to associate with tumorigenesis in...The content of this RSS Feed (c) The Royal Society of Chemistry

GPETAFLR, an octapeptide isolated from Lupinus angustifolius L. protein hydrolysate, promotes the skewing to M2 phenotype in human primary monocytes

Food Funct., 2019, Accepted ManuscriptDOI: 10.1039/C9FO00115H, PaperSergio Montserrat-de la Paz, Ana Lemus-Conejo, Rocio Toscano, Justo Pedroche, Francisco Millán Rodríguez, María del Carmen Millán-LinaresThe present study aimed to test the mechanisms by which GPETAFLR, released from the enzymatic hydrolysis of lupine protein, may modulate the inflammatory response and plasticity in human primary monocytes....The content of this RSS Feed (c) The Royal Society of Chemistry

A sulfated polysaccharide from Gracilaria Lemaneiformis regulate cholesterol and bile acid metabolism in high-fat diet mice

Food Funct., 2019, Accepted ManuscriptDOI: 10.1039/C9FO00263D, PaperShiming Huang, Daorui Pang, Xiong Li, Lijun You, Zhengang Zhao, Peter C. K. Cheung, Mingwei Zhang, Dong LiuThis study aims to evaluate the regulation of lipid metabolism and its mechanism of a sulfated polysaccharide from Gracilaria Lemaneiformis (GLP). The results showed that GLP could significantly decrease the...The content of this RSS Feed (c) The Royal Society of Chemistry

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